If the client has employed Designers to produce brochures or even coloured Business Cards, you can get an idea of their Corporate Preferences. However if there are no clues like that to go on, you need to sit down with some form of Colour Demo so you can easily change background and font colours until between you some combination of colours comes out ahead.
If it is Your Own Site then please yourself and go along with what You like combined with your judgement of what is acceptable and/or pleasing to your target market. sector.
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